Agapie Group

Agapie Group Inorganic, Organometallic and Bioinorganic Chemistry
Synthesis, Mechanism and Catalysis

Research in the Agapie laboratory is targeted toward developing new materials and catalysts for sustainable technologies by using inspiration from biological systems. Some of the most fascinating catalysts in Nature display complex inorganic cofactors, sometimes in combination with organic cofactors, and perform chemical transformations (water reduction and oxidation, carbon dioxide reduction, dinitrogen reduction, dioxygen reduction) that are arguably prerequisites for the advance of society in the current context of limiting energy resources and environmental concerns. The group’s approach to these chemical transformations is centered on the synthesis and study of metal complexes relevant to catalysis. Given the scale of the potential applications, we focus on studies of inexpensive and abundant first-row transition metals. To these ends we have developed new methodologies for the synthesis of complex inorganic targets and have performed mechanistic studies to understand the properties and reactivity of these compounds. The graphic above highlights some of our results and approaches.

Papers

113) Gwendolyn A. Bailey and Theodor Agapie. "Terminal, Mo Carbide and Carbyne Reactivity: H2 Cleavage, B-C Bond Activation, and C-C Coupling" Organometallics., 2021 Article ASAP. link
112) Gwendolyn A. Bailey, Joshua A. Buss, Paul H. Oyala, and Theodor Agapie. "Terminal, Open-Shell Mo Carbide and Carbyne Complexes: Spin Delocalization and Ligand Non-innocence" J. Am. Chem. Soc., 2021 Article ASAP. link
111) Linh N. V. Le, Gwendolyn A. Bailey, Anna G. Scott, Theodor Agapie. "Cluster Models of FeMoco with Sulfide and Carbyne Ligands: Effect of Interstitial Atom in Nitrogenase Active Site" ChemRxiv, 2021 link
110) Jessica Sampson, Meaghan Bruening, Muhammed Naseem Akhtar, E. A. Jaseer, Rajesh Theravalappil, Nestor Garcia, and Theodor Agapie. "Copolymerization of Ethylene and Long-Chain Functional α-Olefins by Dinuclear Zirconium Catalysts" Organometallics, 2021 40, 1854-1858. link
109) Heui Beom Lee, Angela A. Shiau, David A. Marchiori, Paul H. Oyala, Byung-Kuk Yoo, Jens T. Kaiser, Douglas C. Rees, R. David Britt, and Theodor Agapie. "CaMn3IVO4 Cubane Models of the Oxygen Evolving Complex: Spin Ground States S < 9/2 and the Effect of Oxo Protonation" Angew. Chem. Int. Ed., 2021, 60, 17671-17679. link
108) Shuoyan Xiong, Manar M. Shoshani, Xinglong Zhang, Heather A. Spinney, Alex J. Nett, Briana S. Henderson, Thomas F. Miller III, Theodor Agapie. "Efficient Copolymerization of Acrylate and Ethylene with Neutral P, O-Chelated Nickel Catalysts: Mechanistic Investigations of Monomer Insertion and Chelate Formation" J. Am. Chem. Soc. 2021, 143, 6516-6527 link
107)Arnaud Thevenon, Alonso Rosas-Hernández, Alex M. Fontani Herreros, Theodor Agapie, and Jonas C. Peters. "Dramatic HER Suppression on Ag Electrodes via Molecular Films for Highly Selective CO2 to CO Reduction" ACS Catalysis. 2021, 11, 4530-4537 link
106)Adnan Ozden, Yuhang Wang, Fengwang Li, Mingchuan Luo, Jared Sisler, Arnaud Thevenon, Alonso Rosas-Hernández, Thomas Burdyny, Yanwei Lum, Hossein Yadegari, Theodor Agapie, Jonas C. Peters, Edward H. Sargent, and David Sinton. "Cascade CO2 Electroreduction Enables Efficient Carbonate-free Production of Ethylene" Joule. 2021, 5, 706-719 link
105)Nathanael A. Hirscher, Charles H. Arnett, Paul H. Oyala, and Theodor Agapie. "Characterization of Cr-Hydrocarbyl Species via Pulse EPR in the Study of Ethylene Tetramerization Catalysis" Organometallics 2020, 39, 4420-4429 link
104)Ryan D. Ribson, Gyeongshin Choi, Ryan G. Hadt, and Theodor Agapie. "Controlling Singlet Fission with Coordination Chemistry-Induced Assembly of Dipyridyl Pyrrole Bipentacenes" ACS Cent. Sci. 2020, 6, 2088-2096 link
103)Charles H. Arnett, Isabel Bogacz, Ruchira Chatterjee, Junko Yano, Paul H. Oyala, and Theodor Agapie. “Mixed-Valent Diiron μ -Carbyne, μ -Hydride Complexes: Implications for Nitrogenase" J. Am. Chem. Soc., 2020, 44, 18795-18813 link
102)Adnan Ozden, Fengwang Li, F. Pelayo Garcı́a de Arquer, Alonso Rosas-Hernández, Arnaud Thevenon, Yuhang Wang, Sung-Fu Hung, Xue Wang, Bin Chen, Jun Li, Joshua Wicks, Mingchuan Luo, Ziyun Wang, Theodor Agapie, Jonas C. Peters, Edward H. Sargent, and David Sinton. “High-Rate and Efficient Ethylene Electrosynthesis Using a Catalyst/Promoter/Transport Layer" ACS Energy Lett., 2020, 5, 2811-2818 link
101)Manar M. Shoshani and Theodor Agapie. “Ligand Architecture for Triangular Metal Complexes: A High Oxidation State Ni3 Cluster with Proximal Metal Arrangement" Chem. Commun., 2020, 56, 11279-1282 link
100)Ruomeng Wan, Joshua A. Buss, Kyle T. Horak, and Theodor Agapie. “A Hemilabile Diphosphine Pyridine Pincer Ligand: σ- and π-Binding in Molybdenum Coordination Complexes" Polyhedron, 2020, 187, 114631. link (Special issue celebrating John Bercaw's 75th birthday)
99)Charles H. Arnett and Theodor Agapie. “Activation of an Open Shell, Carbyne-Bridged Diiron Complex Toward Binding of Dinitrogen" J. Am. Chem. Soc., 2020, 142, 10059-10068 link
98)Dae-Hyun Nam, Phil De Luna, Alonso Rosas-Hernández, Arnaud Thevenon, Fengwang Li, Theodor Agapie, Jonas C. Peters, Osama Shekhah, Mohamed Eddaoudi, and Edward H. Sargent. “Molecular enhancement of heterogeneous CO2 reduction" Nature Materials, 2020, 19, 266-276. link
97)Heui Beom Lee, David A. Marchiori, Ruchira Chatterjee, Paul H. Oyala, Junko Yano, R. David Britt, and Theodor Agapie. “S = 3 Ground State for a Tetranuclear MnIV4O4 Complex Mimicking the S3 State of the Oxygen Evolving Complex" J. Am. Chem. Soc., 2020, 142, 3753-3761. link
96)Fengwang Li, Arnaud Thevenon, Alonso Rosas-Hernández, Ziyun Wang, Yilin Li, Christine M. Gabardo, Adnan Ozden, Cao Thang Dinh, Jun Li, Yuhang Wang, Jonathan P. Edwards, Yi Xu, Christopher McCallum, Lizhi Tao, Zhi-Qin Liang, Mingchuan Luo, Xue Wang, Huihui Li, Colin P. O'Brien, Chih-Shan Tan, Dae-Hyun Nam, Rafael Quintero-Bermudez, Tao-Tao Zhuang, Yuguang C. Li, Zhiji Han, R. David Britt, David Sinton, Theodor Agapie, Jonas C. Peters, and Edward H. Sargent. “Molecular Tuning of CO2-to-Ethylene Conversion" Nature, 2020, 577, 509-513. link (commentaries in Chemical & Engineering News, Science Daily, and Caltech News)
95)Zachary Mathe, Dimitrios A. Pantazis, Heui Beom Lee, Richard Gnewkow, Benjamin E. Van Kuiken, Theodor Agapie, and Serena DeBeer. “Calcium Valence-to-Core X-ray Emission Spectroscopy: A Sensitive Probe of Oxo Protonation in Structural Models of the Oxygen-Evolving Complex" Inorg. Chem., 2019, 58, 16292-16301. link
94)Charles H. Arnett, Jens T. Kaiser, and Theodor Agapie. “Remote Ligand Modifications Tune Electronic Distribution and Reactivity in Site-Differentiated, High-Spin Iron Clusters: Flipping Scaling Relationships" Inorg. Chem., 2019, 58, 15971-15982. link
93)Arnaud Thevenon, Alonso Rosas-Hernández, Jonas Peters, and Theodor Agapie. “In-situ Nanostructuring and Stabilization of Polycrystalline Copper by an Organic Salt Additive Promotes Electrocatalytic CO2 Reduction to Ethylene" Angew. Chem. Int. Ed., 2019, 58, 16952-16958. link
92)Jessica Sampson, Gyeongshin Choi, Muhammad Naseem Akhtar, E.A. Jaseer, Rajesh Theravalappil, Nestor Garcia, and Theodor Agapie. “Early Metal Di(pyridyl) Pyrrolide Complexes with Second Coordination Sphere Arene-π Interactions: Ligand Binding and Ethylene Polymerization" ACS Omega, 2019, 4, 15879-15892. link
91)Joshua A. Buss, Gwendolyn A. Bailey, Julius Oppenheim, David G. VanderVelde, William A. Goddard III, and Theodor Agapie. “CO Coupling Chemistry of a Terminal Mo Carbide: Sequential Addition of Proton, Hydride, and CO Releases Ethenone" J. Am. Chem. Soc., 2019, 141, 15664-15674. link
90)Christopher Reed and Theodor Agapie. “A Terminal FeIII-Oxo in a Tetranuclear Cluster: Effects of Distal Metal Centers on Structure and Reactivity" J. Am. Chem. Soc., 2019, 141, 9479-9484. link
89)Heui Beom Lee and Theodor Agapie. “Redox Tuning via Ligand-Induced Geometric Distortions at a YMn3O4 Cubane Model of the Biological Oxygen Evolving Complex" Inorg. Chem., 2019, 58, 14998-15003. link
88) Heui Beom Lee, Paul H. Oyala, and Theodor Agapie. “Synthesis, Electronic Structure, and Spectroscopy of Multinuclear Mn Complexes Relevant to the Oxygen Evolving Complex of Photosystem II; in Oxygen Production and Reduction in Artificial and Natural Systems; James Barber, Alexander V. Ruban, and Peter J. Dixon, Ed.; World Scientific: Singapore, 2019; pp. 259-283. link
87)Nathanael A. Hirscher, Danny Perez Sierra, and Theodor Agapie. “Robust Chromium Precursors for Catalysis: Isolation and Structure of a Single-Component Ethylene Tetramerization Precatalyst" J. Am. Chem. Soc., 2019, 141, 6022-6029. link
86)Davide Lionetti, Sandy Suseno, Emily Y. Tsui, Luo Lu, Troy A. Stich, Kurtis M. Carsch, Robert J. Nielsen, William A. Goddard, III, R. David Britt, and Theodor Agapie. “Effects of Lewis Acidic Metal Ions (M) on Oxygen-Atom Transfer Reactivity of Heterometallic Mn3MO4 Cubane and Fe3MO(OH) and Mn3MO(OH) Clusters" Inorg. Chem., 2019, 58, 2336-2345. link
85)Nathanael A. Hirscher, Jay A. Labinger, and Theodor Agapie. “Isotopic Labelling in Ethylene Oligomerization: Addressing the Issue of 1-Octene vs. 1-Hexene Selectivity" Dalton Trans., 2019, 48, 40-44. link
84)Heui Beom Lee, Angela A. Shiau, Paul H. Oyala, David A. Marchiori, Sheraz Gul, Ruchira Chatterjee, Junko Yano, R. David Britt, and Theodor Agapie. “Tetranuclear [MnIIIMn3IVO4] Complexes as Spectroscopic Models of the S2 State of the Oxygen Evolving Complex in Photosystem II” J. Am. Chem. Soc., 2018, 140, 17175-17187. link
83)Joshua A. Buss, Masanari Hirahara, Yohei Ueda, and Theodor Agapie. “Molecular Mimics of Heterogeneous Metal Phosphides: Thermochemistry, Hydride-Proton Isomerism, and HER Reactivity” Angew. Chem. Int. Ed., 2018, 57, 16329-16333. link
82)Choon Heng Low, Jeffrey N. Rosenberg, Marco A. Lopez, and Theodor Agapie. “Oxidative Coupling with Zr(IV) Supported by a Non-Innocent Anthracene-Based Ligand: Application to the Catalytic Cotrimerization of Alkynes and Nitriles to Pyrimidines” J. Am. Chem. Soc., 2018, 140, 11906-11910. link
81)Christopher J. Reed and Theodor Agapie. “Thermodynamics of Proton and Electron Transfer in Tetranuclear Clusters with Mn-OH2/OH Motifs Relevant to H2O Activation by the Oxygen Evolving Complex in Photosystem II” J. Am. Chem. Soc., 2018, 140, 10900-10908. link
80)Joshua A. Buss, David G. VanderVelde, and Theodor Agapie. “Lewis Acid Enhancement of Proton Induced CO2 Cleavage: Bond Weakening and Ligand Residence Time Effects” J. Am. Chem. Soc., 2018, 140, 10121-10125. link
79)Joshua A. Buss, Christine Cheng, and Theodor Agapie. “A Low-Valent Molybdenum Nitride: Reduction Promotes Carbonylation Chemistry” Angew. Chem. Int. Ed. 2018, 57, 9670-9674. link
78)Charles H. Arnett, Matthew J. Chalkley, and Theodor Agapie. “A Thermodynamic Model for Redox-Dependent Binding of Carbon Monoxide at Site-Differentiated, High Spin Iron Clusters” J. Am. Chem. Soc. 2018, 140, 5569-5578. link
77)Naoki Shida, Joshua A. Buss, and Theodor Agapie. “Mild electrochemical synthesis of metal phosphides with dibenzo-7-phosphanorbornadiene derivatives: mechanistic insights and application to proton reduction in water” Chem. Commun. 2018, 54, 767-770. link
76)Nathanael A. Hirscher and Theodor Agapie. “Stoichiometrically Activated Catalysts for Ethylene Tetramerization using Diphosphinoamine-Ligated Cr Tris(hydrocarbyl) Complexes” Organometallics 2017, 36, 4107-4110. link
75)Christopher J. Reed and Theodor Agapie. “Tetranuclear Fe Clusters with a Varied Interstitial Ligand: Effects on the Structure, Redox Properties, and Nitric Oxide Activation” Inorg. Chem. 2017, 56, 13360-13367. link
74)Joshua A. Buss, Paul H. Oyala, and Theodor Agapie. “Terminal Molybdenum Phosphides with d-Electrons: Radical Character Promotes Coupling Chemistry” Angew. Chem. Int. Ed. 2017, 56, 14502-14506. link
73)Markus Kubin, Jan Kern, Sheraz Gul, Thomas Kroll, Ruchira Chatterjee, Heike Löchel, Franklin D. Fuller, Raymond G. Sierra, Wilson Quevedo, Christian Weniger, Jens Rehanek, Anatoly Firsov, Hartawan Laksmono, Clemens Weninger, Roberto Alonso-Mori, Dennis L. Nordlund, Benedikt Lassalle-Kaiser, James M. Glownia, Jacek Krzywinski, Stefan Moeller, Joshua J. Turner, Michael P. Minitti, Georgi L. Dakovski, Sergey Koroidov, Anurag Kawde, Jacob S. Kanady, Emily Y. Tsui, Sandy Suseno, Zhiji Han, Ethan Hill, Taketo Taguchi, Andrew S. Borovik, Theodor Agapie, Johannes Messinger, Alexei Erko, Alexander Föhlisch, Uwe Bergmann, Rolf Mitzner, Vittal K. Yachandra, Junko Yano, and Philippe Wernet. “Soft x-ray absorption spectroscopy of metalloproteins and high-valent metal-complexes at room temperature using free-electron lasers” Structural Dynamics 2017, 4, 054307. link
72)Graham de Ruiter, Kurtis M. Carsch, Michael K. Takase, and Theodor Agapie. “Selectivity of C-H versus C-F Bond Oxygenation by Homo- and Heterometallic Fe4, Fe3Mn, and Mn4 Clusters” Chem. Eur. J. 2017, 23, 10744-10749. link
71)Zhiji Han, Ruud Kortlever, Hsiang-Yun Chen, Jonas C. Peters, and Theodor Agapie. “CO2 Reduction Selective for C≥2 Products on Polycrystalline Copper with N-Substituted Pyridinium Additives” ACS Central Science 2017 3, 853-859. link
70)Kurtis M. Carsch, Graham de Ruiter, and Theodor Agapie. “Intramolecular C-H and C-F Bond Oxygenation by Site-Differentiated Tetranuclear Manganese Models of the OEC” Inorg. Chem. 2017, 56, 9044-9054. link
69)Zhiji Han, Kyle T. Horak, Heui Beom Lee, and Theodor Agapie. “Tetranuclear Manganese Models of the OEC Displaying Hydrogen Bonding Interactions: Application to Electrocatalytic Water Oxidation to Hydrogen Peroxide” J. Am. Chem. Soc. 2017, 139, 9108-9111. link
68)Jessica Sampson, Gyeongshin Choi, Muhammed Naseem Akhtar, E. A. Jaseer, Rajesh Theravalappil, Hassan Ali Al-Muallem, and Theodor Agapie. “Olefin Polymerization by Dinuclear Zirconium Catalysts Based on Rigid Teraryl Frameworks: Effects on Tacticity and Copolymerization Behavior” Organometallics 2017, 36, 1915-1928. link
67)Heui Beom Lee, Emily Y. Tsui, and Theodor Agapie. “CaMn4O2 model of the biological oxygen evolving complex: synthesis by cluster expansion on low symmetry ligand” Chem. Commun. 2017, 53, 6832-6835. link
66)Alejo M. Lifschitz, Nathanael A. Hirscher, Heui Beom Lee, Joshua A. Buss, and Theodor Agapie. “Ethylene Tetramerization Catalysis: Effects of Aluminum-Induced Isomerization of PNP to PPN Ligands” Organometallics 2017, 36, 1640-1648. link
65)Graham de Ruiter, Kurtis M. Carsch, Sheraz Gul, Ruchira Chatterjee, Niklas B. Thompson, Michael K. Takase, Junko Yano, and Theodor Agapie. “Accelerated Oxygen Atom Transfer and C-H Bond Oxygenation by Remote Redox Changes in Fe3Mn-Iodosobenzene Adducts” Angew. Chem. Int. Ed. 2017, 129, 4850-4854. link
64)Suho Jung, Ruud Kortlever, Ryan J. R. Jones, Michael F. Lichterman, Theodor Agapie, Charles C. L. McCrory, and Jonas Peters. “Gastight Hydrodynamic Electrochemistry: Design for a Sealed Rotating Disk Electrode Cell” Anal. Chem. 2017, 89, 581-585. link
63)Joshua A. Buss and Theodor Agapie “Mechanism of Molybdenum Mediated Carbon Monoxide Deoxygenation and Coupling: Mono- and Dicarbyne Complexes Precede C-O Bond Cleavage and C-C Bond Formation” J. Am. Chem. Soc. 2016, 138, 16466-16477. link
62)Paul Kelley, Guy A. Edouard, Sibo Lin, and Theodor Agapie “Lewis Acid Accelerated Aryl Ether Bond Cleavage with Ni: Orders of Magnitude Rate Enhancement by AlMe3Chem. Eur. J. 2016, 22, 17173-17176. link
61)Po-Heng Lin, Emily Y. Tsui, Fatemah Habib, Muralee Murugesu, and Theodor Agapie “Effect of the Mn Oxidation State on Single-Molecule-Magnet Properties: MnIII vs MnIV in Biologically Inspired DyMn3O4 Cubanes” Inorg. Chem. 2016, 55, 6095-6099. link
60)Justin T. Henthorn and Theodor Agapie “Modulation of Proton-Coupled Electron Transfer through Molybdenum-Quinonoid Interactions” Inorg. Chem. 2016, 55, 5337-5342. link
59)Davide Lionetti, Graham de Ruiter, and Theodor Agapie “A Trans-Hyponitrite Intermediate in the Reductive Coupling and Deoxygenation of Nitric Oxide by a Tricopper-Lewis Acid Complex” J. Am. Chem. Soc. 2016, 138, 5008-5011. link
58)Kyle T. Horak and Theodor Agapie “Dioxygen Reduction by a Pd(0)-Hydroquinone Diphosphine Complex” J. Am. Chem. Soc. 2016, 138, 3443-3452. link
57)Graham de Ruiter, Niklas B. Thompson, Michael K. Takase, and Theodor Agapie “Intramolecular C-H and C-F Bond Oxygenation Mediated by a Putative Terminal Oxo Species in Tetranuclear Iron Complexes” J. Am. Chem. Soc. 2016, 138, 1486-1489. link
56)Joshua A. Buss and Theodor Agapie “Four-electron deoxygenative reductive coupling of carbon monoxide at a single metal site” Nature, 2016, 529, 72-75. link
55)Jacob S. Kanady, Jose Mendoza-Cortes, William A. Goddard III, and Theodor Agapie. “Oxygen-Evolving Complex of Photosystem II: Insights from Computation and Synthetic Models” in Metalloproteins: Structure, Functions, and Interactions; Art E. Cho and William A. Goddard III, Ed.; CRC Press: Boca Raton, FL, 2015; pp. 165-204.
54)Guy A. Edouard, Paul Kelley, David E. Herbert, and Theodor Agapie “Aryl Ether Cleavage by Group 9 and 10 Transition Metals: Stoichiometric Studies of Selectivity and Mechanism” Organometallics 2015, 34, 5254-5277. link
53)Graham de Ruiter, Niklas B. Thompson, Davide Lionetti, and Theodor Agapie “Nitric Oxide Activation by Distal Redox Modulation in Tetranuclear Iron Nitrosyl Complexes” J. Am. Chem. Soc. 2015, 137, 14094-14106. link
52)Kyle T. Horak, Sibo Lin, Jonathan Rittle, and Theodor Agapie “Heterometallic Effects in Trinuclear Complexes Supported by p-Terphenyl Diphosphine Ligands” Organometallics 2015, 34, 4429-4432. link
51)Kyle T. Horak, David G. VanderVelde, and Theodor Agapie “Tuning of Metal Complex Electronics and Reactivity by Remote Lewis Acid Binding to a π-Coordinating Pyridine Diphosphine Ligands” Organometallics 2015, 34, 4753-4765. link
50)Sandy Suseno, Charles C. L. McCrory, Rosalie Tran, Sheraz Gul, Junko Yano, and Theodor Agapie “Molecular Mixed-Metal Manganese Oxido Cubanes as Precursors to Heterogeneous Oxygen Evolution Catalysts” Chem. Eur. J. 2015, 21, 13420-13430. link
49)Justin T. Henthorn, Sibo Lin, and Theodor Agapie “Combination of Redox-Active Ligand and Lewis Acid for Dioxygen Reduction with π-Bound Molybdenum Quinoid Complexes” J. Am. Chem. Soc. 2015, 137, 1458-1464. link
48)Po-Heng Lin, Michael K. Takase, and Theodor Agapie “Investigations of the Effect of the Non-Manganese Metal in Heterometallic-Oxido Cluster Models of the Oxygen Evolving Complex of Photosystem II: Lanthanides as Substitutes for Calcium” Inorg. Chem. 2015, 54, 59-64. link
47)Vlad Martin-Diaconescu, Marcello Gennari, Bertrand Gerey, Emily Tsui, Jacob Kanady, Rosalie Tran, Jacques Pécaut, Dimitrios Maganas, Vera Krewald, Eric Gouré, Carole Duboc, Junko Yano, Theodor Agapie, Marie-Noelle Collomb, and Serena DeBeer “Ca K-Edge XAS as a Probe of Calcium Centers in Complex Systems” Inorg. Chem. 2015, 54, 1283-1292. link
46)Davide Lionetti and Theodor Agapie “Inorganic Chemistry: How Calcium Affects Oxygen Formation” Nature 2014. link
45)Justin T. Henthorn and Theodor Agapie “Dioxygen Reactivity with a Ferrocene-Lewis Acid Pairing: Reduction to a Boron Peroxide in the Presence of Tris(pentafluorophenyl)borane” Angew. Chem. Int. Ed. 2014, 53, 12893-12896. link
44)Jacob S. Kanady, Po-Heng Lin, Kurtis M. Carsch, Robert J. Nielsen, Michael K. Takase, William A. Goddard III, and Theodor Agapie “Towards Models for the Full Oxygen-Evolving Complex of Photosystem II by Ligand Coordination to Lower the Symmetry of the Mn3CaO4 Cubane: Demonstration that Electronic Effects Facilitate Binding of a Fifth Metal” J. Am. Chem. Soc. 2014, 136, 14373-14376. link
43)Joshua A. Buss, Guy A. Edouard, Christine Cheng, Jade Shi, and Theodor Agapie “Molybdenum Catalyzed Ammonia Borane Dehydrogenation: Oxidation State Specific Mechanisms” J. Am. Chem. Soc. 2014, 136, 11272-11275. link
42)Emily Y. Tsui and Theodor Agapie “Carbon Dioxide Cleavage by a Ni2 Complex Supported by a Binucleating Bis(N-Heterocyclic Carbene) Framework” Polyhedron 2014, 8, 103-110. link (Special issue celebrating John Bercaw's 70th birthday)
41)Madalyn R. Radlauer and Theodor Agapie “Bimetallic Zirconium Amine Bis(phenolate) Polymerization Catalysts: Enhanced Activity and Tacticity Control for Polyolefin Synthesis” Organometallics 2014, 33, 3247-3250. link
40)Kyle T. Horak, Alexandra Velian, Michael W. Day, and Theodor Agapie “Arene Non-Innocence in Dinuclear Complexes of Fe, Co, and Ni Supported by a para-Terphenyl Diphosphine” Chem. Commun. 2014, 50, 4427-4429. link
39)David E. Herbert, Davide Lionetti, Jonathan Rittle, and Theodor Agapie “Heterometallic Triiron-Oxo/Hydroxo Clusters: Effect of Redox-Inactive Metals” J. Am. Chem. Soc. 2013, 135, 19075-19078. link
38)Emily Y. Tsui, Jacob S. Kanady, and Theodor Agapie “Synthetic Cluster Models of Biological and Heterogeneous Manganese Catalysts for O2 Evolution” Inorg. Chem. 2013, 52, 13833-13848. link (Award Paper also featured on the cover)
37)Sandy Suseno, Kyle T. Horak, Michael W. Day, and Theodor Agapie “Trinuclear Nickel Complexes with Metal–Arene Interactions Supported by Tris- and Bis(phosphinoaryl)benzene Frameworks” Organometallics 2013, 32, 6883-6886. link
36)Sibo Lin, David E. Herbert, Alexandra Velian, Michael W. Day, and Theodor Agapie “Dipalladium(II) Terphenyl Diphosphine Complexes as Models for Two-Site Adsorption and Activation of Organic Molecules” J. Am. Chem. Soc. 2013, 135, 15830-15840. link
35)David E. Herbert, Nadia C. Lara, Theodor Agapie “Arene C-H Amination at Nickel Terphenyl-Diphosphine Complexes with Labile Metal-Arene Interactions” Chem. Eur. J. 2013, 19, 16453-16460. link
34)Jacob S. Kanady, Rosalie Tran, Jamie A. Stull, Luo Lu, Troy A. Stich, Michael W. Day, Junko Yano, David R. Britt, and Theodor Agapie “Role of Oxido Incorporation and Ligand Lability in Exapanding Redox Accessibility of Structurally Related Mn4 Clusters” Chem. Sci. 2013, 4, 3986-3996. link
33)Sandy Suseno and Theodor Agapie “Intramolecular Arene C-H to C-P Functionalization by Nickel(II) and Palladium(II)” Organometallics 2013, 32, 3161-3164. link
32)Paul Kelley, Michael W. Day, and Theodor Agapie “Hydrogen Evolution Catalyzed by Aluminum-Bridged Cobalt Diglyoximate Complexes” Eur. J. Inorg. Chem. 2013, 3840-3845. link (special issue on small-molecule activation by reactive metal complexes; article featured on the cover with cover profile)
31)Emily Y. Tsui and Theodor Agapie “Reduction Potentials of Heterometallic Manganese-Oxido Cubane Complexes Modulated by Redox-Inactive Metals” Proc. Natl. Acad. Sci. U.S.A. 2013, 110, 10084-10088. link
30)Madalyn R. Radlauer, Aya K. Buckley, Lawrence M. Henling, and Theodor Agapie “Bimetallic Coordination Insertion Polymerization of Unprotected Polar Monomers: Copolymerization of Amino Olefins and Ethylene by Dinickel Bisphenoxyiminato Catalysts” J. Am. Chem. Soc. 2013, 135, 3784-3787. link
29) Emily Y. Tsui, Rosalie Tran, Junko Yano, and Theodor Agapie “Redox-inactive metals modulate the reduction potential in heterometallic manganese—oxido clusters” Nature Chem. 2013, 5, 293-299. link (commentaries in Nature Chemistry and Caltech News)
28)Jacob S. Kanady, Jose L. Mendoza-Cortes, Emily Y. Tsui, Robert J. Nielsen, William A. Goddard, III, and Theodor Agapie “Oxygen Atom Transfer and Oxidative Water Incorporation in Cuboidal Mn3MOn Complexes Based on Synthetic, Isotopic Labeling, and Computational Studies” J. Am. Chem. Soc. 2013, 135, 1073-1082. link
27)Davide Lionetti, Michael W. Day, and Theodor Agapie “Metal-Templated Ligand Architectures for Trinuclear Chemistry: Tricopper Complexes and Their O2 Reactivity” Chem. Sci. 2013, 4, 785-790. link
26)Paul Kelley, Madalyn R. Radlauer, Abraham J. Yanez, Michael W. Day, and Theodor Agapie “Metallomacrocycles as ligands: synthesis and characterisation of aluminium-bridged bisglyoximato complexes of palladium and iron” Dalton Trans. 2012, 41, 8086-8092 (Young Talent Issue) link
25)Paul Kelley, Sibo Lin, Guy Edouard, Michael W. Day, and Theodor Agapie “Nickel-Mediated Hydrogenolysis of C—O Bonds of Aryl Ethers: What Is the Source of the Hydrogen?” J. Am. Chem. Soc. 2012, 134, 5480-5483. link
24)Madalyn R. Radlauer, Michael W. Day, and Theodor Agapie “Dinickel Bisphenoxyiminato Complexes for the Polymerization of Ethylene and α-Olefins” Organometallics, 2012, 31, 2231-2243. link
23)Madalyn R. Radlauer, Michael W. Day, and Theodor Agapie “Bimetallic Effects on Ethylene Polymerization in the Presence of Amines: Inhibition of the Deactivation by Lewis Bases” J. Am. Chem. Soc. 2012, 134, 1478-1481. link
22)Charlotte A. Whited, Jeffrey J. Warren, Katherine D. Lavoie, Emily E. Weiner, Theodor Agapie, Jay R. Winkler, and Harry B. Gray “Gating NO Release from Nitric Oxide Synthase” J. Am. Chem. Soc. 2012, 134, 27-30. link
21)Jacob S. Kanady, Emily Y. Tsui, Michael W. Day, and Theodor Agapie “A Synthetic Model of the Mn3Ca Subsite of the Oxygen-Evolving Complex in Photosystem II” Science 2011, 333, 733-736. link (commentaries in Chemical & Engineering News, Chemistry World, and Education in Chemistry)
20)Steven T. Chao, Nadia C. Lara, Sibo Lin, Michael W. Day and Theodor Agapie “Reversible Halide-Modulated Nickel–Nickel Bond Cleavage: Metal–Metal Bonds as Design Elements for Molecular Devices” Angew. Chem. Int. Ed. 2011, 50, 7529–7532. link
19)Emily Y. Tsui, Jacob S. Kanady, Michael W. Day, and Theodor Agapie “Trinuclear First Row Transition Metal Complexes of a Hexapyridyl, Trialkoxy 1,3,5-Triarylbenzene Ligand” Chem. Commun. 2011, 47, 4189-4191 link
18)Sibo Lin, Michael W. Day, and Theodor Agapie “Nickel Hydrides Supported by a Non-Innocent Diphosphine Arene Pincer: Mechanistic Studies of Nickel−Arene H-Migration and Partial Arene Hydrogenation” J. Am. Chem. Soc. 2011, 133, 3828-3831. link
17)Emily Y. Tsui, Michael W. Day, and Theodor Agapie “Trinucleating Copper: Synthesis and Magnetostructural Characterization of Complexes Supported by a Hexapyridyl 1,3,5-Triarylbenzene Ligand” Angew. Chem. Int. Ed. 2011, 50, 1668-1672 link
16)Theodor Agapie “Selective Ethylene Oligomerization: Recent Advances in Chromium Catalysis and Mechanistic Investigations” Coord. Chem. Rev. 2011, 255, 861-880. link
15)Sibo Lin and Theodor Agapie “Cross-Coupling Chemistry at Mononuclear and Dinuclear Nickel Complexes” Synlett 2011, 1, 1-5. link
14)Alexandra Velian, Sibo Lin, Alexander J. M. Miller, Michael W. Day and Theodor Agapie “Synthesis and C–C Coupling Reactivity of a Dinuclear NiI–NiI Complex Supported by a Terphenyl Diphosphine” J. Am. Chem. Soc. 2010, 132 (18), 6296-6297. link
Undergraduate, Graduate, and Post-Doctoral Work ↓
13)Ian A. Tonks, Daniel Tofan, Edward C. Weintrob, Theodor Agapie, and John E. Bercaw “Zirconium and Titanium Propylene Polymerization Precatalysts Supported by a Fluxional C2-Symmetric Bis(anilide)pyridine Ligand” Organometallics 2012, 31 1965-1974. link
12)Theodor Agapie, Sandy Suseno, Joshua J. Woodward, Stefan Stoll, R. David Britt, and Michael A. Marletta “NO formation by a catalytically self-sufficient bacterial nitric oxide synthase from Sorangium cellulosumsProc. Natl. Acad. Sci. USA 2009, 106 (38), 16221-16226. link
11)Theodor Agapie, Michael W. Day, and John E. Bercaw “Synthesis and Reactivity of Tantalum Complexes Supported by Bidentate X2 and Tridentate LX2 Ligands having Two Phenolates Linked to Pyridine, Thiophene, Furan, and Benzene Connectors – Mechanistic Studies of the Formation of a Tantalum Benzylidene and Insertion Chemistry for Tantalum Carbon Bonds” Organometallics 2008, 27 (23), 6123-6142. link
10)Theodor Agapie, Lawrence M. Henling, Antonio G. DiPasquale, Arnold L. Rheingold, and John E. Bercaw “Zirconium and Titanium Complexes Supported by Tridentate LX2 Ligands having Two Phenolates Linked to Furan, Thiophene, and Pyridine Donors: Precatalysts for Propylene Polymerization and Oligomerization” Organometallics 2008, 27 (23), 6245-6256. link
9)Theodor Agapie, Jay A. Labinger, and John E. Bercaw “Mechanistic Studies of Olefin Trimerization with Chromium Catalysts – Deuterium Labeling and Studies of Regiochemistry Using a Model Cromacyclopentane Complex” J. Am. Chem. Soc. 2007, 129 (46), 14281-14295. link 
8)Theodor Agapie and John E. Bercaw “Cyclometallated Tantalum Diphenolate Pincer Complexes: Intramolecular C-H/M-CH3 σ– Bond Metathesis May Be Faster than O-H/M-CH3 Protonolysis" Organometallics 2007, 26 (12), 2957-2959. link
7)Smaranda C. Marinescu, Theodor Agapie, Michael W. Day, and John E. Bercaw "Group 3 Dialkyl Complexes with Tetradentate (L, L, N, O; L = N, O, S) Monoanionic Ligands – Synthesis and Reactivity" Organometallics 2007, 26 (5), 1178-1190. link 
6)Theodor Agapie, Michael W. Day, Lawrence M. Henling, Jay A. Labinger, and John E. Bercaw “A Chromium Diphosphine System for Catalytic Ethylene Trimerization: Synthetic and Structural Studies of Chromium Complexes with a Nitrogen-Bridged Diphosphine Ligand with ortho-Methoxyaryl Substituents” Organometallics 2006, 25 (11), 2733-2742. link 
5)Theodor Agapie, Susan J. Schofer, Jay A. Labinger, and John E. Bercaw “Mechanistic Studies of the Ethylene Trimerization Reaction with Chromium – Diphosphine Catalysts: Experimental Evidence for a Mechanism Involving Metallacyclic Intermediates” J. Am. Chem. Soc. 2004, 126 (5), 1304-1305. link 
4)Theodor Agapie, Paula L. Diaconescu, and Christopher C. Cummins “Methine (CH) Transfer via a Chlorine Atom Abstraction/Benzene-Elimination Strategy: Molybdenum Methylidyne Synthesis and Elaboration to a Phosphaisocyanide Complex” J. Am. Chem. Soc. 2002, 124 (11), 2412-2413. link 
3)Theodor Agapie, Paula L. Diaconescu, Daniel J. Mindiola and Christopher C. Cummins “Radical Scission of Symmetrical 1,4-Dicarbonyl Compounds: C-C Bond Cleavage with Titanium(IV) Enolate Formation and Related Reactions” Organometallics 2002, 21 (7), 1329-1340. link 
2)Paula L. Diaconescu, Aaron L. Odom, Theodor Agapie and Christopher C. Cummins “Uranium-Group 14 Element Single Bonds: Isolation and Characterization of a Uranium(IV) Silyl Species” Organometallics 2001, 20 (24), 4993-4995. link 
1)Theodor Agapie, Aaron L. Odom, Christopher C. Cummins “In Pursuit of the Molybdenum(III) Tris(thiolate) Fragment: Unusual Structure of a Dimolybdenum μ -Nitrido Complex" Inorg. Chem. 2000, 39 (2), 174-179. link

Patents

5) Agapie T.; Xiong, S.; Bailey, B. C.; Spinney, H. A.; Nett, A. J.; Wilson, D. R.; Klosin, J. "Bis (Phosphino)–Phenoxy Nickel (II) Catalysts for the Copolymerization of Ethylene and Acrylate Monomers" Serial Number: PCT/US2020/046767, Filed: 8/18/2020.
4) Agapie, T.; Rosas-Hernandez, A.; Li, F.; Peters, J. C.; Sargent, E. H.; Thevenon, A "The Stabilization ofa CO-Bound Intermediate via Molecular Tuning Promotes CO2-to-Ethylene Conversion" Serial Number: PCT/US2020/041583, Filed: 7/10/2020.
3) Han, Z.; Kortlever, R.; Chen, H.-C.; Peters, J.C.; Agapie, T.; Rosas-Hernandez, J.A.; Thevenon, A. "Product Selectivity for CO2 Reduction" Patent Serial Number:15/950,150, Filed: 4/10/2018.
2) Radlauer, M.; Wiensch, J.D.; Buckley, A.K.; Agapie, T. "Multi-metallic organometallic complexes, and related polymers, compositions, methods and systems" Patent 9233996.
1) Agapie, T.; Golisz, S.R.; Tofan, D.; Bercaw, J.E. "Non-metallocene organometallic complexes and related methods and systems" Patent US007847099.

Ch102 (S'09, S'10, S'11, S'12, S'13, S'14, S'15, S'16, S'17, Spring 2018)

Intro to Inorganic Chemistry

Ch112 (F'15, F'16, F'17, F'18 Fall 2019)

Inorganic Chemistry

Ch154a (Winter 2020)

Organometallic Chemistry

Course website

Ch212a (S'10, S'12, Spring 2014)

Bioinorganic Chemistry

Course website

Ch5b (F'10, F'11, F'12, F'13, F'16 Fall 2018)

Advanced Techniques of Synthesis and Analysis

Coordination and Organometallic Compounds

Course Manual
Handling of Organometallic Compounds
Swivel Frit Operation (video by Jeff Byers)
Theo Office: 314 Noyes
Laboratory: 301-309 Noyes
Phone: 626-395-3617
Fax: 626-395-4676
E-mail (at caltech.edu): agapie

Administrative Assistant: Margarita Davis
Office: Noyes 134
Phone: 626-395-6856
E-mail (at caltech.edu): davism

Mailing address:
Department of Chemistry, MC 127-72
1200 East California Boulevard
California Institute of Technology
Pasadena, CA 91125

Theodor Agapie was born in 1979 in Bucharest, Romania. He received his B.Sc. degree from Massachusetts Institute of Technology in 2001 and his Ph.D. from California Institute of Technology in 2007. Upon completion of his Ph.D. he moved to University of California, Berkeley as a Miller Postdoctoral Fellow.

Theo developed his passion for chemistry during high school and participated in chemistry competitions; he won two silver medals at the International Chemistry Olympiads as part of the Romanian team. While an undergraduate at MIT, he worked with Professor Christopher C. Cummins for more that three and a half years on atom and fragment transfer chemistry involving metal complexes, on titanium-ketyl radical chemistry, and on DFT computations to detail the electronic structure of synthesized complexes. At graduation, he received the Chemistry Department's Alpha Chi Sigma Award for achievement in research, scholarship, and service to the department. At Caltech, Theo worked under the tutelage of Professor John E. Bercaw on mechanistic and synthetic aspects of chromium-based olefin oligomerization catalysis and on developing new early transition metal nonmetallocene olefin polymerization catalysts. His Ph.D. thesis received Caltech's Chemistry Department Herbert Newby McCoy Award for outstanding contribution to the science of chemistry. Upon graduation, in May 2007, Theo moved to UC Berkeley to work with Professor Michael A. Marletta as a Miller Institute Fellow. There, he focused on mechanistic aspects of biochemical nitric oxide synthesis involving the metalloprotein nitric oxide synthase.

Theo returned to Caltech on February 11, 2009 to start his independent career as Assistant Professor of Chemistry. He was promoted to Professor of Chemistry in December, 2014. Selected awards include the Searle Award (2010), Sloan Fellowship (2012), NSF CAREER Award (2012), ACS Award in Pure Chemistry (2013), Presidential Early Career Award for Scientists and Engineers (PECASE, 2014), and Dreyfus Teacher-Scholar Award (2014).

Post-Doctoral Scholars

PriyabrataPriyabrata Ghana
Postdoctoral Researcher - RWTH Aachen University, 2018-2021
University of Bohn, Ph.D. '17
Indian Institute of Technology, Kanpur, M.Sc. '11
University of Calcutta, B.Sc. '09
HaiHai Dong
University of Michigan, Ph.D. '21
University of Cincinnati, B.S. '16
haitdong
WeixuanWeixuan Nie
University of Michigan, Ph.D. '21
Nanjing Univeristy, M.Sc. '15 B.S. '12
niewx
YueshenYueshen Wu
Yale University, Ph.D. '20
Hong Kong University of Science and Technology, B.S. '15
ywu8

Graduate Students

MeaghanMeaghan Bruening
St. Catherine University '17
B.S. Chemistry
mbruenin
AnnaAnna Scott
Montana State University '17
B.S. Chemistry
ascott
AngelaAngela Shiau
UC Berkeley '17
B.S. Chemistry
ashiau
ShuoyanShuoyan Xiong
USTC '17
B.E. Polymer Materials & Engineering
sxiong
GavinGavin Heim
University of California, San Diego '18
B.S. Biochemistry and Chemistry
gheim
LinhLinh Nguyen Vuong Le
Colgate University '18
B.A. Chemistry and Physics
lle
MikeTianyi (Mike) He
Colgate University '19
B.A. Chemistry and Philosophy
thhe
LienBoi-Lien Nguyen
University of Houston '20
B.S. Chemistry
bnnguyen

Undergraduate Students

AlexAlexandria Hong
Caltech '23
alexandriahong
Tyler"Tyler Fox
Caltech '24
tfox

Post-Doctoral Alumni

ManarManar Shoshani
Now: Assistant Professor University of Texas Rio Grande Valley
University of Windsor, Ph.D. '18, B.S. '13
manar
GwenGwen Bailey
Now: Assistant Professor University of Minnesota Twin Cities
University of Ottawa, Ph.D. '18
University of British Columbia, B.S. '12
gbailey
ArnaudArnaud Thevenon
Now: Assistant Professor Utrecht University
University of Oxford, Ph.D. '17
École Polytechnique Fédérale de Lausanne
M.Sc. '13, B.S. '11
thevarna
Hsiang-YunHsiang-Yun Chen
(Joint with Peters Group)
Now: Formosa Plastics
Texas A&M University Ph.D. '12
National Taiwan University B.S. '06
hchen
ShinGyeongshin Choi
Now: LG

Osaka University Ph.D. '14
Ajou University B.S. '08
ZhijiZhiji Han
Now: Professor - Sun-Yat Sen University

University of Rochester Ph.D. '14
Shantou University B.S. '06
DaveDave E. Herbert
Now: Assistant Professor - University of Manitoba, Canada
Herbert Group Website

University of Bristol Ph.D. '10
University of Toronto M.Sc. '06
University of King's College B.S. '04
RuudRuud Kortlever
Now: Assistant Professor - Delft University of Technology

Leiden University Ph.D. '15, M.Sc. '11, B.S. '09
AlejoAlejo Lifschitz
Now: Dow

Northwestern University Ph.D. '15
Dickinson College B.S. '10
Po-HengPo-Heng Lin
Now: Assistant Professor - National Chung Hsing University, Taiwan
Lin Group Website

University of Ottawa Ph.D. '12
National Tsing Hua University M.S. '04
National Chung Cheng University B.S. '02
SitiSiti Riduan
Now: A-Star Institute of Bioengineering and Nanotechnology
Research Scientist

National University of Singapore
Ph.D. '13
B.S. Chemistry '05
GrahamGraham de Ruiter
Now: Assistant Professor - Technion - Israel Institute of Technology
de Ruiter Group Website

Weizmann Institute of Science Ph.D. '14
Leiden University B.S. '08
NaokiNaoki Shida
Now: Assistant Professor, Tokyo Institute of Technology
Tokyo Institute of Technology Ph.D. '16
Yokohama National University B.S. '11
nshida

Graduate Alumni

RyanRyan Ribson
University of Rochester '14
B.S. Chemistry
rribson
CharlieCharlie Arnett
Now: Jones Day, Washington, D.C.
Caltech Ph.D. '20
Georgetown University '15
B.S. Chemistry
carnett
H.B.Heui Beom Lee
Now: Postdoc, UC Berkeley
Caltech Ph.D. '19
University of Pennsylvania '13
B.S.E. Chemical Engineering and Chemistry
hlee3
MarcusChoon Heng Low (Marcus)
Now: Experimental Drug Development Centre, Singapore
Caltech Ph.D. '19
Imperial College '12
B.S. Chemistry
clow
JessicaJessica Sampson
Now: Postdoc, Princeton University
Caltech Ph.D. '18
University of Chicago '13
B.S. Chemistry
jsampson
ChrisChris Reed
Now: Postdoc, University of Illinois at Urbana-Champaign
Caltech Ph.D. '19
Idaho State University '13
B.S. Chemistry and Biochemistry
creed
NateNate Hirscher
Now: Postdoc, University of Pennsylvania
Caltech Ph.D. '19
University of Virginia '14
B.S. Chemistry
nhirsche
JoshJoshua Buss
Now: Assistant Professor, University of Michigan
Buss Group Website
Caltech Ph.D. '18
Claremont McKenna College '12
B.A. Chemistry
jbuss
StevenSteven Chao
Caltech M.S. '11
University of Texas B.S. '08
GuyGuy A. Edouard
Now: Intel

Caltech Ph.D. '15
Harvard College B.A. '10
JustinJustin Henthorn
Now: Post-Doctoral Scholar, Max Planck Institute

Caltech Ph.D. '16
Ohio University B.S. '10
KyleKyle Horak
Now: Intel

Caltech Ph.D. '16
Cornell University B.A. '10
JacobJacob Kanady
Now: Post-Doctoral Scholar, UC Berkeley

Caltech Ph.D. '14
UC Irvine B.S. '09
PaulPaul Kelley
Now:Assistant Professor, Philander Smith College

Caltech Ph.D. '14
Catholic University of America B.S. '08
SiboSibo Lin
Now: Post-Doctoral Scholar, MIT

Caltech Ph.D. '14
Indiana University B.S. '08
DavideDavide Lionetti
Now:Assistant Professor, Franklin & Marshall College/>
Caltech Ph.D. '15
University of Notre Dame B.S. '09
MaddyMadalyn Radlauer
Now: Assistant Professor - San José State University
Radlauer Group Website

Post-Doctoral Scholar, University of Minnesota
Caltech Ph.D. '14
Stanford University B.S. '08
SandySandy Suseno
Now: Intel

Caltech Ph.D. '14
UC Berkeley B.S. '08
EmilyEmily Tsui
Now: Assistant Professor - University of Notre Dame
Tsui Group Website

Post-Doctoral Scholar, University of Washington
Caltech Ph.D. '14
MIT S.B. '08

Undergraduate Alumni

MyaMya Serrano
WAVE Fellow 2021

Rutgers Univeristy '22
DavidDavid Dumas
WAVE Fellow 2021

UCLA '22
VidhyaVidhya Dev
Now: Graduate Student - Harvard

Caltech '21
vdev
AdrianAdrian Huang
Now: Graduate Student - UC Berkeley

Caltech '20
ajhuang
ElizabethElisabeth Gallmeier
Caltech '21
egallmei
ElinElin Kang
Caltech '23
eskang
ChrisChris Lamartina
Now: Graduate Student - Columbia

Caltech '19
clamarti
SophieSophie Whitmeyer
Now: Graduate Student - UChicago

Caltech '19
swhitmey
MatthewMatthew Zeitlin
Caltech '21
mzeitlin
JulesJules Oppenheim
Now: Graduate Student - MIT
Caltech '21
joppenhe
DavidDavid Adams
Caltech '20
RitaRita Aksenfeld
Caltech '20
MartinMartin Bernat
University College London '10
AyaAya Buckley
Now: Graduate Student - UC Berkeley

Columbia '13
KurtisKurtis Carsch
Now: Graduate Student - Harvard

Caltech '16
GabriellaGabriella Chan
Caltech '20
Chun-SunChung-Sun Chen
Cambridge '13
ChristineChristine Cheng
Now: Graduate Student - USC

Caltech '14
MichaelMichael Desanker
Now: Graduate Student - Northwestern University

MIT '13
BogdanBogdan Dimitriu
Caltech '17
PaigePaige Gannon
Now: Graduate Student - Penn

Caltech '18
pgannon
JenJennifer Karolewski
Now: MIT

Caltech '15
DanielDaniel Kim
Now: Graduate Student - Yale University

Colgate '15
NadiaNadia Lara
Now: Teacher - St. Agnes Academy

Rice Ph.D.
Caltech '12
KatherineKatherine Lee
Now: Graduate Student - University of North Carolina at Chapel Hill

Caltech '15
MarcoMarco Lopez
Now: Graduate Student - UWisconsinMadison

Cal State LA '18
JudyJudy Mou
Caltech '13
EvaEva Nichols
Now: Assistant Professor - University of British Columbia
Nichols Group Website

Post-Doctoral Scholar, Yale University
UC Berkeley Ph.D. '18

Caltech '12
Wei JianWei Jian Ong
Caltech '13
DannyDanny Perez
The University of Texas at San Antonio '19
DianeDiane Rafizadeh
Now: Graduate Student - Penn, MD-PhD(Chem)

Yale University '19
JeffJeffrey Rosenberg
Now: Graduate Student - MIT

Caltech '17
JadeJade Shi
Now: Graduate Student - Stanford University

Caltech '12
DiamondDiamond Thomas
University of Michigan '18
AgnesAgnes Thorarinsdotter
Now: Graduate Student - Northwestern University

University of Iceland '15
AlexAlexandra Velian
Now: Assistant Professor - University of Washington
Velian Group Website

Post-Doctoral Scholar, Columbia University
MIT Ph.D. '14
Caltech B.S. '09
RuomengRuomeng Wan
Caltech '18
rwan
AndreasAndreas Wierschen
Now: Graduate Student - University of North Carolina

University of North Carolina '11
AbrahamAbraham Yanez-McKay
Now: Graduate Student - Northwestern University

Michigan State University '11
VictorYuanchi "Victor" Zhao
Yale University '13

Visiting Scholar Alumni

AimeeAimee Bryan
University of California at Davis Ph.D. '15
NaofumiNaofumi Hara

Graduate Student - Kyoto University
naofumih
MasaMasanari Hirahara
Research Associate - National Defense Academy of Japan
Kyushu University
Ph.D. '11
B.S. '06
hirahara
HitoshiHitoshi Izu
Graduate Student - SOKENDAI
hitoshi
YujiYuji Nishii
Osaka University, Ph.D.
MikuMiku Oi
University of Tokyo, M.Sc. '17
Tokyo University of Science, B.S. '15
miku0720
JihaeJihae Park
Ajou University
Ph.D. Chemistry '14
B.S. Applied Chemistry '09
DavidDavid Schmidl
University of Munich
YoheiYohei Ueda
Osaka University, Ph.D.
DavitDavit Zargarian
Professor - University of Montréal
University of Ottawa, Ph.D. '92
University of Waterloo M.Sc. '87
University of Toronto B.S. '85

Group Photos

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June Lake Retreat February 2015

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Agapie and Marinescu Groups Trip to Piute Pass and Bishop Pass August 2014

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Kearsarge Pass Trip August 2013

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Mono Pass Trip August 2012

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Palisade Glacier Trip August 2011

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Bishop Pass Trip August 2010

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Mono Pass Trip August 2009

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Huntington Beach BBQ July 2009

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Lab Initiation February 2009

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High School Outreach May 2015

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High School Outreach May 2014

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High School Outreach May 2013

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High School Outreach May 2012

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Summer Chemistry Workshop August 2011

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Introduction.pdf
ClockReaction_InitialRates_Student.pdf
ClockReaction_InitialRates_Teacher.pdf
ClockReaction_IntegratedRateLaws_Student.pdf
ClockReaction_IntegratedRateLaws_Teacher.pdf
Data_Plots.xls

High School Outreach May 2011

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High School Outreach May 2010

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